Thermal decomposition
Metal carbonates such as calcium carbonate break down when heated strongly. This is called thermal decomposition. It is a endothermic reaction as heat is required to break chemical bonds in the compound undergoing decomposition.
calcium carbonate
calcium oxide + carbon dioxide
CaCO3
CaO + CO2
Some compound are more difficult to decompose by heating than others. This mean that these compounds are more stable to heat than others.Thermal stability of metal carbonate is in relation to the position of the metal in the reactivity series. The more reactive metals-carbonate are harder to decompose.Metal-carbonate after sodium form metal oxide and carbon dioxide upon heating all in the exception of silver carbonate which decompose into silver and carbon dioxide upon heating.
Metal Carbonate
|
Observation
|
Potassium Carbonate, K2CO3
|
no reaction
|
Sodium Carbonate, Na2CO3
|
no reaction
|
Calcium Carbonate CaCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Magnesium Carbonate MgCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Zinc carbonate ZnCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Iron (ll) carbonate FeCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Lead (II) carbonate PbCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Copper(II) carbonate CuCO3
|
decompose into metal oxide and carbon dioxide upon heating
|
Silver carbonate Ag2CO3
|
decomposes into silver, oxygen gas & carbon dioxide upon heating
|
credits: Chemistry textbook
http://www.bbc.co.uk/schools/gcsebitesize/science/aqa_pre_2011/rocks/limestonerev1.shtml
http://en.wikipedia.org/wiki/Thermal_decomposition